Infanta Luia Carlota was born to the Borbones of Naples-Two Sicilies. She married her maternal uncle Infante Francisco de Paula of Spain who was ten years older. They had 11 children. She was Queen Isabel II's aunt and the sister of Maria Cristina de Borbón who acted as regent. Her Wikipedia articles in Spanish and English are here and here, respectively.
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
1833 Dolores Gómez de las Casas de Tirel, Marquesa de la Ulagares by Vicente López y Portaña (private collection)
1819 Infanta Luisa Carlota de Borbón by Vicente López Portaña (Museo de la Fundación Lázaro Galdiano - Madrid, Spain)
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