Finding her biographical information proved difficult. Her article in thepeerage dates her birth to 1759. If the date of this image is correct, then the sitter is about nine. Her article in geni.com lists her birth date as 1750, consistent with the image.
Grand Ladies
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
Countess Razumovskaya Varvara Petrovna (1750-1824), née Countess Sheremetev by Ivan Petrovich Argunov (location ?)
1763 Catherine II by Feodor Rokotov (State Tretyakov Gallery - Moskva, Russia)
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