She was the daughter of Charlotte Aglaé d'Orléans born in Modena and married another scion of the Orléans family to become another grandmother to the future King Louis Philippe. Her Wikipedia article is here.
Grand Ladies
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
Maria Francisca Pignatelli and Gonzaga, Duchess of Medinaceli by Anton Raphael Mengs (location unknown to gogm)
Marie Thérèse Félicité d'Este, Princess of Modena and future Duchess of Penthi`èvre by ? (location unknown to gogm)
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