This is Infanta Maria Josefa Carmela of Spain whose Wikipedia article is here. She was caught in marital negotiations, with Louis XV among others, and died unmarried.
Grand Ladies
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
Maria Francisca Pignatelli and Gonzaga, Duchess of Medinaceli by Anton Raphael Mengs (location unknown to gogm)
Infanta Maria Josefa de Borbon by Anton Raphael Mengs (location ?)
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