It takes a score card to keep the Maria Luisas straight. This particular Maria Luisa was Infanta of Spain, daughter of Carlos III, who married the future Holy Roman Emperor Leopold II. She moved from Spain into Habsburg lands in Tuscany and lived in Florence for 25 years beginning in 1765. She should not be confused with Maria Luisa of Parma who moved from Italy to Spain. This Maria Luisa's Wikipedia article is here.
Grand Ladies
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
Maria Francisca Pignatelli and Gonzaga, Duchess of Medinaceli by Anton Raphael Mengs (location unknown to gogm)
1764 Infanta Maria Luisa by Anton Rafael Mengs (Kunsthistorisches Museum - Wien, Austria)
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