She came from Ireland and first married the Duke of Hamilton in 1752 and the Marquess of Lorne and later Duke of Argyll, one of the Campbells in a famous feud with the MacDonalds, in 1759 after the death of the first husband. She was a Lady of the Bedchamber to Queen Charlotte and George III created her a Baroness in her own right. Her Wikipedia article is here.
Grand Ladies
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
Maria Francisca Pignatelli and Gonzaga, Duchess of Medinaceli by Anton Raphael Mengs (location unknown to gogm)
1751 Elizabeth Gunning by Richard Houston (National Portrait Gallery - London UK)
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