Her marriage to the Duke of Modena was a disaster and her life was chaotic. She was the Princesse Lamballe's mother-in-law. Her Wikipedia article is here.
Grand Ladies
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ca. 1555 Caterina de' Medici by ? (Galleria degli Uffizi - Firenze, Toscana, Italy)
Maria Francisca Pignatelli and Gonzaga, Duchess of Medinaceli by Anton Raphael Mengs (location unknown to gogm)
Duchess of Modena by Pierre Gobert (private collection)
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