This is one of Goya's later works.
From the museum Web site.
Doña María's dress has dual sleeves and a high neckline fringed by a lace modesty piece in this 1823 Goya. She decorates her curly, almost hurluberlu, coiffure with a hair ornament, possibly a tiara.
Keywords: 1824, Goya, María Martínez de Puga, Spanish, curly coiffure, tiara, straight neckline, chemise, modesty piece, lace, cuffs, dual upper puffed sleeves, necklace, earrings, handkerchief