She came from Ireland and first married the Duke of Hamilton in 1752 and the Marquess of Lorne and later Duke of Argyll, one of the Campbells in a famous feud with the MacDonalds, in 1759 after the death of the first husband. She was a Lady of the Bedchamber to Queen Charlotte and George III created her a Baroness in her own right. Her Wikipedia article is here.
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1556 Catherine de Medici possibly by Agnolo Bronzino
Maria Francisca Pignatelli and Gonzaga, Duchess of Medinaceli by Anton Raphael Mengs (location unknown to gogm)
1750ca. Elizabeth Gunning by Richard Houston (location unknown to gogm)
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