1825 Ann Maria Harriet de Rhodes (1793-1849), full-length, in a white dress and pink chiffon wrap, a wooded landscape beyonf by Sir William Beechey (auctioned by Christie's)

I cannot find a positive lead for her in thepeerage.

From the Christie's Web site.

Napoléonic and Revolutionary style are making a last stand, but conceding ground with an almost natural waistline and A-line skirt. She is probably wearing a corset as well.

Keywords:  1825, Beechey, Ann Maria de Rhodes, curly coiffure, off shoulder vee neckline, qyarter length puffed sleeves, waist band, natural high waistline, A-line skirt, over-skirt, lace, necklace, brooch, shoes, wrap


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